Material Safety Data Sheets Duraguard Price: $0.00 Shipping: $0.00 Part Number: Qty: MATERIAL SAFETY DATA SHEET PT 1325 ME Duraguard WHITMIRE MICRO-GEN RESEARCH LABS. INC. (314) 225-5371 3568 TREE COURT IND. BLVD. EMERGENCY PHONE NUMBER: (800) 424-9300 (CHEMTEC) EFFECTIVE DATE: DECEMBER 26, 1995 INSECTICIDE LIQUID CONCENTRATE EPA REQ. NO.: 499-367 Section 1 - HAZARDOUS INGREDIENTS ACGIH ACGIH OSHA TLV/TWA STEL PEL Chlorpyrifos 20%: CAS #2921-88-2 0.2 rng/M3 NE NE (0,0--DiethyI 0-(3,.5,.6-Trichloro-2-Pyridyl) phosphorothioate Section 2 - PHYSICAL DATA BOILING POINT: NA EVAPORATION RATE: 1 SPECIFIC GRAVITY (H20=1): 0.97 @ 20 C SOLUBILITY IN WATER: Disperses VAPOR PRESSURE: NA APPEARANCE AND ODOR: Beige-yellow liquid. Characteristic Chlorpyrifos odor. PERCENT VOLATILE: 75% VAPOR DENSITY: NA pH: 7.5-8.5 Section 3 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: None (ASTM Designation D-13-10- SPECIAL FIRE FIGHTING PROCEDURES: SST) Tag Open Cup None - water based formulation. FLAMMABLE LIMITS: NA UNUSUAL FIRE AND EXPLOSION HAZARDS : None known. EXTINGUISHING MEDIA: C02; Dry Chemical; Foam H20 Section 4 - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: NE ROUTES OF ENTRY: INHALATION? SKIN? INGESTION? Tertiary Secondary Primary HEALTH HAZARD (ACUTE AND CHRONIC) - SIGNS AND SYMPTOMS OF EXPOSURE: EYE: Product produces mild reversible eve irritation in albino rabbits. SKIN: Product is not a skin irritant for albino rabbits. Primary skin irritation index = 0.00. Acute dermal toxicity (rabbits) LD50> 2.000 mg/kg. Not a primary skin irritant. skin sensitizer or fatiguing agent in guine pigs. INGESTION & INHALATION: Encapsulation greatly reduces the toxicity and irritation potential of the active ingredients. When sprayed, produces particle size larger than considered respirable. Excessive exposure may produce signs of cholinesterase depression. Acute oral toxicity (rats) LD50> 5.000 mg/kg. SIGNS OF CHOLINESTERASE DEPRESSION: Discomfort or tightness in chest, difficulty in breathing, stomach pains. Nausea, vomiting,. Diarrhea, cramps. headache, nervousness, weakness, non-active pinpoint pupils or blurred vision. Symptoms may, not occur until 1-8 hours after exposure. CARCINOGENICITY: NTP? IARC MONOGRAPH? OSHA REGULATED? No No No EMERGENCY AND FIRST AID PROCEDURES: IF SWALLOWED: Call a physician or poison control center immediately. Drink one or two glasses of water and induce vomiting by touching back of throat with finger. Repeat until vomit fluid is clear. Do not induce vomiting or give anything by mouth to an unconscious person. IF INHALED: Remove patient to fresh air. Apply artificial respiration if indicated. Seek medical attention. IF ON SKIN: Wash affected areas with plenty of soap and water. Seek medical attention if irritation persists. IF IN EYES: Immediately flush with plenty of water. Seek medical attention if irritation persists. NOTE TO PHYSICIAN: If symptoms of cholinesterase inhibition are present. Atropine Sulfate is antidotal. 2-PAM is also antidotal and may be administered in con-junction with Atropine. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known. Section 5 - REACTIVITY DATA STABILITY: Stable under normal use conditions. HAZARDOUS DECOMPOSITION PRODUCTS: NA HAZARDOUS POLYMERIZATION: Will not occur. Section 6 - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain and absorb spills with inert material such as sand, calcium carbonate, clay or sawdust. Do not contaminate waterways. Dispose absorbent in accordance with Federal and local regula-tions. WASTE DISPOSAL METHOD: Container is not refillable. Triple rinse. Puncture container and discard in sanitary landfill. EMERGENCY TELEPHONE NUMBER OF CHEMTREC: (800)424-9300 (for transportation spills) Section 7 - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: None required. Avoid breathing spray mist VENTILATION: LOCAL EXHAUST: None required. MECHANICAL: None required. SPECIAL: None required. OTHER: Ventilate area after treatment. PROTECTIVE GLOVES: Applicators and other handlers, and early reentry require waterproof gloves. EYE PROTECTION: None required. OTHER PROTECTIVE EQUIPMENT: Applicators and other handlers must also wear long-sleeved shirt and long pants and shoes plus socks. Early reentry calls for coveralls and shoes plus socks. Section 8 - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep out of reach of children. Do not store below 32 F. Do not store near heat or open flame. Do not puncture. . OTHER PRECAUTIONS: Wash thoroughly after using. Avoid contamination of food, utensils, and food preparation areas. Remove pets and cover or remove aquariums before using. Ventilate area after - treatment is completed. Keep out of lakes, streams and ponds. Product is toxic to bees. Section 9 - HEALTH RATING INFORMATION HEALTH - l FLAMMABILITY - 0 REACTIVITY - 1 Section 10 - SARA TITLE III / SECTION 313 / SUPPLIER NOTIFICATION THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372 THIS PRODUCT CONTAINS NO SECTION 313 TOXIC CHEMICALS Section 11 - DOT SHIPPING INFORMATION PROPER SHIPPING NAME: RQ Environmentally Hazardous Substance, Liquid NOS (Chlropyrifos) PACKING GROUP: III HAZARD CLASS: 9 UN I.D. NO.: UN 3082 ********************************************************************* NA - Not Applicable NE - Not Established DEL - Permissible Exposure Limit ACL - Acceptable Ceiling Level MPC - Maximum Peak Concentration SouthWest Plantscape Products 265 Durley Ave Camarillo, Ca 93010 Telephone: (800) 333-7977 (SWPP) Fax: (805) 988-4975 E-Mail: sales@SouthWestPlantscape.com